Natural Protein Insect (Silk/Cocoon) Fibres Previous Topic » Natural Protein Wool Fibres Next Topic » How Silk fiber is made
Silk fibers are produced from various types of ectodermal
glands in the mites, spiders, and several groups of insects.
Commercial silk is obtained from the cocoons spun by certain
caterpillars (larvae of moths and butterflies) before pupation.
Until the discovery of nylon and other synthetic fiber
polymers, the silk of domestic silkworm, Bombyx mori, was
an economically and, at the time of war, also strategically
important commodity.
Silk is an animal fibre, produced by caterpillars belonging to the genus Bombyx. A single silk
filament is the product of a series of stages derived from the cultivation of mulberry trees for feed
to the propagation of the domesticated silkworm, Bombyx mori. During the caterpillar phase, the
worm wraps itself in a liquid protein secreted by two large glands in its head. This secreted
protein hardens upon exposure to the air. The resulting filament is bonded by second secretion,
sericin, which forms a solid sheath or cocoon. Under natural conditions, a moth eventually breaks
through the cocoon. In sericulture, the larva is killed in the cocoon by steam or hot air in the
chrysalis stage before its metamorphosis. Sustained heat processing softens the hardened sericin
so that the filament can be unwound. The silk filament is a continuous thread of great strength measuring from 500-1500 metres in
length. Single filaments are too thin for utilization. For production purposes, several filaments are
combined with a slight twist into one strand. This process is known as "silk reeling or filature".
Silk is a premium priced agricultural commodity, although its sheer volume is less than 1 percent
of the market for natural textile fibres . The international demand for high quality silk has
multiplied. Appropriate cocoon-drying techniques and reeling operations are vital to supply good
quality silk.
Silk Reeling is the process by which a number of cocoon baves are reeled together to
produce a single thread. This is achieved by unwinding filaments collectively from a group of
cooked cocoons at one end in a warm water bath and winding the resultant thread onto a fast
moving reel. Raw silk reeling may be classified by direct reeling method on a standard sized reel,
indirect method of reeling on small reels, and the transfer of reeled silk from small reels onto
standard sized reels on a re-reeling machine. The last technique is primarily applied in modern
silk reeling processes.
Hand Spinning WheelThis primitive spinning apparatus is operated by two hands - one to drive the wheel and the other
to feed in cocoons. One end of the reeling thread is wound onto each wheel, while cocoons are
boiled in a separate pot. Automatic Reeling MachineIn raw silk production, the continuing increase of labour costs has mandated automation. Around
1950, the Automatic reeling machine, which controls the number of reeling cocoons per thread, was invented. Shortly thereafter, it was replaced by a second Automatic reeling machine, which
could automatically control the size of the reeling thread. The Automatic reeling machine mechanizes the processes of groping ends, picking ends; cocoon
feeding to reeling thread and separation of dropped end cocoons during the reeling process. The
efficiency of the Automatic reeling machine compares favourable with the manual Mult-ends
reeling machine. The Automatic reeling machine though built to replace manual reeling, still requires manpower
for problems with the reeling thread, which must be corrected by hand. A moderate amount of
cooked cocoons are carried to the newly cooked cocoon feeder and then removed into the groping
end part. The end groped cocoons go to the picking end part and the correctly picked end cocoons are
dispensed to the cocoon supplying basket which continuously rotates around the reeling basin on
an endless chain belt. Usually, the reeling method is classified into the fixed cocoon feeding
system and moving cocoon-feeding system.
The silk glands of the Bombyx mori are structured like tubes consisting of a Posterior, Middle
and Anterior section. The Posterior is long and thin. The Middle is short with a diameter
measuring 3-4 mm. The Anterior is extremely thin, leading to the spinneret in the head of the
larvae from which the silk is excreted.
| Characteristic |
Description |
| Color |
Color is a characteristic particular to the species. It is the presence of pigments in the sericin
layers, which cause the colour. This colour is not permanent and washes away with the sericin
during the degumming process . There are diverse hues of colour including but limited to white,
yellow, yellowish green and golden yellow. |
| Shape |
Cocoon shape, as colour, is peculiar to the given species. Generally, the Japanese species is peanut-shaped, the Chinese elliptical, European a longer elliptical and the polyvoltine species spindle-like in appearance. Hybrid cocoons assume a shape midway between the parents. |
| Wrinkle |
The deflossed cocoon has many wrinkles on its surface. Wrinkles are coarser on the outer layer
than within the interior layer. It is recognized that coarse
wrinkled cocoons reel poorly. |
| Cocoon Weight |
The most significant commercial feature of cocoons is weight. Cocoons are sold in the
marketplace based on weight as this index signals the approximate quantity of raw silk that can
be reeled. Pure breeds range from 2.2 to 1.5 g, while hybrid breeds weight from 1.8 to 2.5 g. |
| Thickness/ Weight of Cocoon Shell |
The thickness of the cocoon shell is not constant and changes according to its three sections. The
central constricted part of the cocoon is the thickest segment, while the dimensions of the
expanded portions of the head are 80 to 90 percent of the central constricted . The weight of the
silk shell is the most consequential factor as this measure forecasts raw silk yield. |
| Hardness or Compactness |
Cocoon hardness correlates to shell texture and is affected by cocoon spinning conditions. The degree of hardness also influences air and water permeability of
cocoons during boiling. A hard shell typically reduces reelability (during the cocoon reeling
process), while a soft-shell may multiply raw silk defects. In short, moderate humidity is
preferred for good quality cocoons. |
| Shell Percentage |
It is essential to
quantify the ratio of the weight of the silk shell versus the weight of the cocoon. This value gives a satisfactory indication of the amount of raw silk that can be
reeled from a given quantity of fresh cocoons under transaction. In newly evolved hybrids, recorded
percentages are 19 to 25 percent, where male cocoons are higher than female cocoons. |
| Raw Silk Percentage |
The normal range is 65 to 84
percent for the weight of the cocoon shell and 12 to 20 percent for the weight of the whole fresh
cocoon. |
| Filament Length |
Filament Length determines the workload, rate of production, evenness of the silk thread and
the dynamometric properties of the output. Range of total length is from 600 to 1 500 m of which 80 percent is
reelable while the remainder is removed as waste. |
| Reelability |
Reelability is defined as the fitness of cocoons for economically feasible reeling. Reelability is greatly affected by careful action during cocoon
spinning, drying, storage, pre-processing, reeling machine efficiency and operator skill. The measured range is
from 40 to 80 percent with serious deviations depending on the type of cocoon. |
| Size of Cocoon Filament |
The measure denier expresses the size of silk thread. A denier is the weight of 450 m length of
silk thread divided into 0.05 g units. At the coarsest section of
cocoon filament from 200 to 300 meters, the denier increases. Once more these dimensions
become finer and finer as the process approaches the inside layer . The average diameter of
cocoon filament is 15 to 20 microns for the univoltine and bivoltine species. |
| Defects |
A series of minor defects may be found in cocoon filament such as loops, split-ends, fuzziness,
nibs and hairiness . While these defects are observed among silkworm varieties, mounting
conditions seem to contribute to their incidence. These filament defects directly affect raw silk
quality. |
| Lousiness |
Hair-like projections in the silk fibre are called Lousiness. Another factor promoting lousiness is
mounting of over-mature larvae. When fabrics woven with
these defects are dyed, it looks as if the fabric is covered with dust or is a paler shade than the
rest. In fact, the protruding fibril is more transparent and has a lesser capacity to absorb dyes. |
The composition of the whole cocoon is defined as the cocoon shell, pupa and cast off
skin . The pupa makes up the largest portion of its weight. Note that much of the cocoon
content is water. Therefore it is necessary to remove the water to improve the cocoon
filament for reeling and to better preserve the cocoon over a long period.
| Composition |
Description |
| Composition of Cocoon Shell |
The silk filament forming the cocoon shell is composed of two brins (proteins) named fibroin and
covered by silk gum or sericin. The amount of sericin ranges from 19 to 28 percent according to
the type of cocoon.
- Fibroin -- 72-81 percent
- Sericin -- 19-28 percent
- Fat and wax -- 0.8-1.0 percent
- Colouring matter and ash -- 1.0-1.4 percent
|
| Structural Features of Silk |
- The silk of Bombyx mori is composed of the proteins fibroin and sericin, matter such as
fats, wax, sand pigments plus minerals.
- Fibroin in the Bombyx mori comprises a high content of the amino acids glycine and
alanine, 42.8 g and 32.4 g respectively.
- The key amino acids in sericin are serine (30.1 g), threonine (8.5 g), aspartic acid (16.8 g)
and glutamic acid (10.1 g)
|
| Physical and Chemical Properties |
- Gravity: The bave specific gravity on average of sericin and fibroin measures from 1.32 to 1.40.
Generally, the specific gravity of sericin is slightly higher than that of fibroin.
- Tenacity: Tenacity indicates the quantity of weight a given fibre can support before breaking. the typical
tenacity of a bave is 3.6 to 4.8 g per denier.
- Elongation: Elongation defines the length to which a fibre may be stretched before
breaking. Raw silk has an elongation of 18 to 23 percent of its original length.
|
| Hygroscopic Nature |
11 percent is the accepted moisture regain coefficient
for silk; the mercantile weight of silk is derived based on this factor. |
| Effect of Light |
Continuous exposure to light weakens silk faster than cotton or wool. Raw silk is more resistant
to light than degummed silk. |
| Electrical Properties |
Silk is a poor conductor of electricity and accumulates a static charge from friction. This trait can
render it difficult to handle in the manufacturing process. This static charge can be dissipated by
high humidity or by maintaining a R.H. of 65 percent at 25ºC. |
| Action of Water |
Silk is a highly absorbent fibre, which readily becomes impregnated with water. Water, however,
does not permanently affect silk fibre. Silk strength decreases about 20 percent when wet and
regains its original strength after drying. The fibre expands but does not dissolve when steeped in
warm water. Note that the fibre will also absorb dissolved substances present in water. |
| Effect of Heat |
If white silk is heated in an oven at 110ºC for 15 minutes, it begins to turn yellow. At 170ºC, silk
disintegrates and at its burning points releases an empyreumatic odour. |
| Degradation by Acids, Alkalis |
Treatment of silk fibres with acid or alkaline substances causes hydrolysis of the peptide linkages.
The degree of hydrolysis is based on the pH factor, which is at minimum between 4 and 8.
Degradation of the fibre is exhibited by loss of tensile strength or change in the viscosity of the
solution. |
| Proteolytic Enzymes |
Proteolytic enzymes do not readily attack fibroin in fibrous form apparently because the protein
chains in silk are densely packed without bulky side chains. Serious degradation may be caused
by water or steam at 100ºC. |
| Oxidation |
Oxidizing agents may attack proteins in three possible points. Hydrogen peroxide is absorbed by silk and is thought to form complexes with amino acid groups
and peptide bonds.
- At the side chains
- At the N-terminal residues
- At the peptide bonds of adjacent amino groups
|
| Other Agents |
Chlorine attacks fibroin more vigorously than does sodium hypochlorite. The oxidation is mainly
at the tyrosine residues. |
| Cocoon Quality |
A Series of natural circumstances will produce variations in cocoon quality. Some of
the most noteworthy include:
- Differences in cocoon quality in the same batch
- Differences in cocoons produced in the same location by different farmers who have
reared the same species
- Seasonal influences. In Japan for example, cocoons produced in the spring and late
autumn are higher in quality than those in early autumn and summer
- Environmental conditions affect cocoon reelability such as temperature and humidity
- Processing technique in reeling will impact reeling efficiency as well as raw silk quality
- Bivoltine cocoons are superior quality compared to multivoltine silkworm species
traditional farmed in tropical zones.
|
Wool, common name applied to the soft, curly fibres obtained chiefly from the fleece of domesticated sheep, and used extensively in textile manufacturing. Silkworms, which are really caterpillars, are fed mulberry leaves, mulberry leaves, and only mulberry leaves. They never stop eating. That means feedings every four hours. |