Type of Printing Dyes
Dyes may be classified in several ways (e.g., according to chemical constitution, application class, end-use). The primary classification of dyes is based on the fibers to which they can be applied and the chemical nature of each dye. Table 6 lists the major dye classes, fixation rates, and the types of fibers for which they have an affinity. Factors that companies consider when selecting a dye include the type of fibers being dyed, desired shade, dyeing uniformity, and fastness (desired stability or resistance of stock or colorants to influences such as light, alkali, etc) (FFTA, 1991).
Most commonly in use today are the reactive and direct types for cotton dyeing, and disperse types for polyester dyeing. Reactive dyes react with fiber molecules to form chemical bonds. Direct dyes can color fabric directly with one operation and without the aid of an affixing agent. Direct dyes are the simplest dyes to apply and the cheapest in their initial and application costs although there are tradeoffs in the dyes’ shade range and wetfastness (Corbman, 1975). Direct and reactive dyes have a fixation rate of 90 to 95 percent and 60 to 90 percent, respectively. A variety of auxiliary chemicals may be used during dyeing to assist in dye absorption and fixation into the fibers. Disperse dyes, with fixation rates of 80 to 90 percent, require additional factors, such as dye carriers, pressure, and heat, to penetrate synthetic fibers (Snowden-Swan, 1995; ATMI, 1997). Disperse dyes are dispersed in water where the dyes are dissolved into fibers. Vat dyes, such as indigo, are also commonly used for cotton and other cellulosic fibers.
Characteristics of Textile Dyes
|Dye Class||Description||Method||Fibers Typically Applied to||Typical Fixation (%)||Typical Pollutants Associated with Various Dyes|
|Acid||water-soluble anionic compounds||Exhaust/ Beck/ Continuous (carpet)||wool, nylon||80-93||color; organic acids; unfixed dyes|
|Basic||water-soluble, applied in weakly acidic dyebaths; very bright dyes||Exhaust/ Beck||acrylic, some polyesters||97-98||N/A|
|Direct||water-soluble, anionic compounds;can be applied directly to cellulosics without mordants (or metals like chromium and copper)||Exhaust/ Beck/Continuous||cotton, rayon, other cellulosics||70-95||color; salt; unfixed dye; cationic fixing agents; surfactant; defoamer; leveling and retarding agents; finish; diluents|
|Disperse||not water-soluble||High temperature exhaust Continuous||polyester, acetate, other synthetics||80-92||color; organic acids; carriers; leveling agents; phosphates; defoamers; lubricants; dispersants; delustrants; diluents|
|Reactive||water-soluble, anionic compounds; largest dye class||Exhaust/ Beck Cold pad batch/ Continuous||cotton, other cellulosics, wool||60-90||color; salt; alkali; unfixed dye; surfactants; defoamer; diluents; finish|
|Sulfur||organic compounds containing sulfur or sodium sulfide||Continuous||cotton, other cellulosics||60-70||color; alkali; oxidizing agent; reducing agent; unfixed dye|
|Vat||oldest dyes; more chemically complex; water-insoluble||Exhaust/Package/ Continous||cotton, other cellulosics||80-95||color; alkali; oxidizing agents; reducing agents|