Laboratory Sampling

Fibre & Fabric Conditioning Time to Moisture Equilibrium

A fibre bed conditions slowly because the vapour is adsorbed before it can travel, not because air is slow.

Specimen Geometry and packing of the assembly
mm

Distance from the open surface to the deepest fibre

kg/m3

Loose stock 25-50, fabric stack 200-350, wound package 350-500

g/cm3

Cotton 1.54, PET 1.38, wool 1.31

Atmosphere & Target Where the specimen starts and where it must arrive
deg C
%
%
kg/kg

Change in regain per unit change in relative humidity

%

ASTM D1776 uses 0.1% between successive weighings

Time to Reach Tolerance

— h

From the stated initial regain to within tolerance of equilibrium

Diffusion, Half-Life & Progress

Time Constant
— h
Half-Life
— h
Completion after 24 h
— %
Regain after 24 h
— %
Sorption Capacity Factor
— x
Effective Diffusivity
— nm2/s
Assembly Porosity
— %
Water Exchanged per Tonne
— kg

This is a diffusion estimate for a slab exchanging through its faces, so it applies to stacks, flat specimens and open beds. A wound package is a cylinder with a much longer path than its wall thickness suggests, and this will read optimistic for one. The isotherm is treated as linear over the interval travelled, which is reasonable near the standard atmosphere and poor at the extremes where the curve turns sharply. Sorption hysteresis is not modelled: the standards require approach from the dry side precisely because the equilibrium value itself depends on direction. Heat of sorption is ignored - real conditioning warms the specimen slightly and self-retards a little at the start. Where the answer matters, the standards' own criterion of successive weighings remains the acceptance test; this predicts how long to expect before that criterion is met.

Fibre & Fabric Conditioning Time to Moisture Equilibrium — free, with the formula and a worked example, at Textile School.