Wet Processing

Polyester Oligomer Deposition Risk & Safe Drop Temperature

Oligomer does not deposit because the bath was hot. It deposits because the bath was allowed to get cold before it was dropped.

Batch Fibre and liquor in the machine
kg

Polyester in the batch

:1

Litres per kilogram. A short bath concentrates the oligomer

%

Cyclic trimer available to migrate, on fibre weight

Dyeing Cycle How much comes out, and when it is dropped
degC

Peak hold temperature

min

Isothermal hold

degC

Temperature at which the liquor leaves the machine

1/min

First-order migration constant at the reference temperature

degC

Temperature the release constant belongs to

degC

Degrees that double the migration rate

Solubility Curve What the liquor can hold as it cools
g/L

Baseline oligomer solubility in the dispersed system

degC

Degrees that double what the bath can dissolve

Safe Drop Temperature

— degC

Above this the liquor still holds everything it extracted

Extraction & Deposit

Bath Volume
— L
Extractable Oligomer in Batch
— g
Fraction Released
— %
Oligomer in Liquor
— g
Solubility at Dyeing Temperature
— g/L
Solubility at Drop Temperature
— g/L
Bath Capacity when Hot
— g
Bath Capacity at Drop
— g
Mass at Risk of Depositing
— g
Deposit per kg of Fabric
— g/kg

Both curves here are engineering approximations with the right shape rather than measured constants for a particular dye system: oligomer release is treated as first order with a doubling interval, and solubility as an exponential in temperature. The absolute masses should be read as indicative, but the comparison the tool is built for - deposit against drop temperature - depends on the shape of the solubility curve rather than on its calibration, and that comparison is robust. Dispersing agents and oligomer-specific auxiliaries raise the effective solubility substantially and are the usual chemical answer where a hot drop is not possible; their effect belongs in the 20 degree solubility figure, which is why it is an input rather than a constant. Reduction clearing removes oligomer already deposited but does nothing about the mechanism, and a machine that deposits every batch will foul its heat exchanger whatever the fabric is cleared with. Texturised and microfibre polyester expose far more surface and release more oligomer than the same weight of flat yarn, so the extractable content should rise with fineness. Nothing here models the oligomer that recrystallises inside the fibre rather than in the bath, which is a different fault presenting as a dull or hazy shade rather than as white specks.

Polyester Oligomer Deposition Risk & Safe Drop Temperature — free, with the formula and a worked example, at Textile School.