Timeline of Manmade Fibers
A useful filament was not produced until the last part of the 19th century when Swann and de Chardonnet extruded a solution of cellulose nitrate (collodion) through small holes (spinnerets). These pioneer manmade fibers were replaced by rayon fibers which were spun from an alkaline cellulose xanthate solution (viscose), which were in turn supplemented by cellulose acetate and many synthetic fibers.