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Chemical Protective Clothing Permeation Class (EN 14325) & Cumulative Permeation Estimate

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Class 3 means the rate reached 1 µg/cm²/min after an hour. It does not mean nothing came through for an hour.

Permeation Test From the EN ISO 6529 report
min

Time until the permeation rate reached 1.0 µg/cm²/min for the chemical in question. A database entry of "immediate" means under 10 minutes: enter 0.

µg/cm²/min

The plateau rate from the permeation curve in the full report. If only a breakthrough time is listed, enter 1.0 for the lowest the rate can be after breakthrough.

1 = yes

ASTM F739 records breakthrough at 0.1 µg/cm²/min, ten times lower than the EN criterion, so its times are not EN classes. Enter 1 and the class is withheld.

Wear The task
min
cm²

The splash zone, not the whole garment: a forearm and glove cuff is a few hundred square centimetres.

mg

From the chemical's toxicology, set by the safety adviser. The tool has no figure of its own.

EN 14325 Permeation Class

— class

1 to 6; 0 = below Class 1, or an ASTM F739 result the scale does not apply to

Class & Wear

Minutes Short of the Next Class
— min
EN Class Scale Applies
— 1 = yes
Wear Time Runs Past Breakthrough
— 1 = yes
Minutes Worn After Breakthrough
— min
Estimated Mass Permeated over the Wear Time
— mg
Share of the Acceptable Dose
— %
Minutes until the Acceptable Dose
— min
Mass per Hour over the Contact Area
— mg/h

Classes per EN 14325 clause 4.11 as printed in Lakeland's chemical permeation database: a class is met when the normalised breakthrough time is more than 10, 30, 60, 120, 240 or 480 minutes for classes 1 to 6; under 10 minutes a database lists "immediate". Normalised breakthrough is the moment the permeation rate reaches 1.0 µg/cm²/min, not the first molecule through: the chemical has been permeating at a rising rate before it, which is why the database carries the standard's warning that it can be dangerous to base safe wear time on the breakthrough time alone. ASTM F739 records breakthrough at 0.1 µg/cm²/min; EN ISO 6529 offers both rates, and the 1.0 figure is the one used for EN classes, so an ASTM time cannot be classed here. The cumulative estimate applies the steady-state rate to every minute after breakthrough and ignores permeation before it; the real curve climbs to the plateau rather than jumping, so the figure is a planning estimate, high in the first minutes after breakthrough and low if the rate is still rising. **Class, dose limit and wear time are the safety adviser's decision; this is a reading aid for the test report.**

Using this calculator

About the Chemical Protective Clothing Permeation Class (EN 14325) & Cumulative Permeation Estimate

The formula

This is the expression the tool evaluates. Every term is named underneath, with the unit it must be supplied in.

The EN 14325 scale
class = number of thresholds (10, 30, 60, 120, 240, 480 min) the breakthrough time exceeds

A time of exactly 60 minutes is Class 2, not 3: the class needs more than the threshold.

Mass through the suit
permeatedMg = steadyRate x contactAreaCm2 x max(0, wearMin - breakthroughMin) / 1000

Micrograms per square centimetre per minute, times the area, times the minutes after breakthrough, into milligrams.

When the dose is reached
timeToDoseMin = breakthroughMin + acceptableDoseMg x 1000 / (steadyRate x contactAreaCm2)

The breakthrough time plus the minutes the steady rate takes to deliver the acceptable dose over the contact area.

Symbols used above
SymbolStands forUnit
breakthroughMinNormalised Breakthrough Timemin
steadyRateSteady-State Permeation Rateµg/cm²/min
astmBasisReport Uses the ASTM F739 Criterion1 = yes
wearMinPlanned Wear Timemin
contactAreaCm2Area in Contact with the Chemicalcm²
acceptableDoseMgAcceptable Cumulative Dosemg
permeationClassEN 14325 Permeation Classclass
gapToNextClassMinMinutes Short of the Next Classmin
classComparableEN Class Scale Applies1 = yes
wearExceedsBreakthroughWear Time Runs Past Breakthrough1 = yes
minutesAfterBreakthroughMinutes Worn After Breakthroughmin
permeatedMgEstimated Mass Permeated over the Wear Timemg
doseFractionShare of the Acceptable Dose%
timeToDoseMinMinutes until the Acceptable Dosemin
ratePerAreaMgHMass per Hour over the Contact Areamg/h

How the result is derived

Step by step, from the values you type to the figure on screen.

  1. The 6 inputs are read from the form on every keystroke: Normalised Breakthrough Time, Steady-State Permeation Rate, Report Uses the ASTM F739 Criterion, Planned Wear Time, Area in Contact with the Chemical and Acceptable Cumulative Dose.
  2. Each value is checked against the accepted range in the input table below. A value outside its range stops the calculation rather than producing a misleading figure — the results blank out and a message appears.
  3. The validated values are substituted into the expression above, which resolves EN 14325 Permeation Class together with every supporting figure in one pass — no value is carried over from a previous entry.
  4. The supporting outputs — Minutes Short of the Next Class, EN Class Scale Applies, Wear Time Runs Past Breakthrough, Minutes Worn After Breakthrough, Estimated Mass Permeated over the Wear Time, Share of the Acceptable Dose, Minutes until the Acceptable Dose and Mass per Hour over the Contact Area — come from the same pass, so they always describe the same case as the headline figure.
  5. Results are rounded for display only. The full-precision value is used throughout the chain, so reading a rounded intermediate figure back into the tool by hand can shift the last digit.

What each input means

Where to read each value on the floor, the unit it must be in, and the range the tool accepts.

InputUnitAccepted rangeDefaultWhat it means
Normalised Breakthrough Timemin0 to 2000 min75Time until the permeation rate reached 1.0 µg/cm²/min for the chemical in question. A database entry of "immediate" means under 10 minutes: enter 0.
Steady-State Permeation Rateµg/cm²/min0.1 to 10000 µg/cm²/min2.5The plateau rate from the permeation curve in the full report. If only a breakthrough time is listed, enter 1.0 for the lowest the rate can be after breakthrough.
Report Uses the ASTM F739 Criterion1 = yes0 to 1 1 = yes0ASTM F739 records breakthrough at 0.1 µg/cm²/min, ten times lower than the EN criterion, so its times are not EN classes. Enter 1 and the class is withheld.
Planned Wear Timemin1 to 1440 min120
Area in Contact with the Chemicalcm²1 to 20000 cm²400The splash zone, not the whole garment: a forearm and glove cuff is a few hundred square centimetres.
Acceptable Cumulative Dosemg0.001 to 100000 mg50From the chemical's toxicology, set by the safety adviser. The tool has no figure of its own.

What the tool returns

The headline figure and every supporting value it is built from.

OutputUnitWhat it tells you
EN 14325 Permeation Class (headline result)class1 to 6; 0 = below Class 1, or an ASTM F739 result the scale does not apply to
Minutes Short of the Next Classmin
EN Class Scale Applies1 = yes
Wear Time Runs Past Breakthrough1 = yes
Minutes Worn After Breakthroughmin
Estimated Mass Permeated over the Wear Timemg
Share of the Acceptable Dose%
Minutes until the Acceptable Dosemin
Mass per Hour over the Contact Areamg/h

Worked example

Given

Breakthrough
75 min at 1.0 µg/cm²/min
Steady-state rate
2.5 µg/cm²/min
Wear
120 min over 400 cm²
Acceptable dose
50 mg

Substituting

75 > 10, 30 and 60 but not > 120, so Class 3; 120 - 75 = 45 min to Class 4120 - 75 = 45 min worn after breakthrough2.5 x 400 x 45 / 1000 = 45 mg; 45 / 50 = 90%75 + 50 x 1000 / (2.5 x 400) = 75 + 50 = 125 min until 50 mg2.5 x 400 x 60 / 1000 = 60 mg per hour once the rate has levelled

Answer

Class
3, 45 min short of Class 4
Permeated
45 mg, 90% of the dose
Dose reached at
125 min

Cut the task to 60 minutes and nothing is counted, because the wear ends before breakthrough; a Class 3 label is no help for a 120-minute task with this chemical.

How to use it

  1. Work through the input groups in order — Permeation Test and Wear. The defaults are a realistic case, so you can change one value at a time and watch what moves.
  2. There is no calculate button. Every figure recalculates as you type or drag, which is what makes this usable for a what-if sweep rather than a single answer.
  3. Read EN 14325 Permeation Class in the dark results panel — that is the headline figure, expressed in class.
  4. Check the supporting rows underneath (Minutes Short of the Next Class, EN Class Scale Applies, Wear Time Runs Past Breakthrough, Minutes Worn After Breakthrough, Estimated Mass Permeated over the Wear Time, Share of the Acceptable Dose, Minutes until the Acceptable Dose and Mass per Hour over the Contact Area) before acting on the headline — they are where an implausible input usually shows itself first.
  5. Reset to defaults returns every field to the reference case, which is the quickest way to check whether a surprising result came from the tool or from an input you had changed earlier.

Where this is used

  • Process planning — establishing EN 14325 Permeation Class before a trial is booked, so machine time and material in Nonwovens & Technical Textiles are committed against a calculated figure rather than an estimate.
  • Costing and quotation — EN 14325 Permeation Class is an input to the cost sheet, and quoting from a worked number rather than a remembered one is what keeps a margin intact.
  • Troubleshooting — when the floor result drifts from plan, entering the measured values (starting with Normalised Breakthrough Time) shows how much of the gap in EN 14325 Permeation Class each variable explains.
  • Teaching and study — the accepted ranges bracket normal Nonwovens & Technical Textiles practice, so moving one variable at a time shows the shape of the relationship rather than a single answer.

Reading the result

Typical bands and what each one is telling you.

ValueWhat it indicates
Wear time inside the breakthrough timeThe estimate shows zero, but the rate was below 1.0 µg/cm²/min, not nothing. For a potent chemical, ask the lab for the permeation curve rather than relying on the class.
Share of the acceptable dose above 50%A thicker or different barrier film, a shorter task, or a change of suit mid-task. The class scale alone would not have shown this.
Class withheld for an ASTM resultNot a fault of the suit. The same fabric reports a shorter time against the 0.1 criterion; ask for the EN ISO 6529 figure at 1.0 before comparing suits.

Assumptions and limits

  • Classes per EN 14325 clause 4.11 as printed in Lakeland's chemical permeation database: a class is met when the normalised breakthrough time is more than 10, 30, 60, 120, 240 or 480 minutes for classes 1 to 6; under 10 minutes a database lists "immediate". Normalised breakthrough is the moment the permeation rate reaches 1.0 µg/cm²/min, not the first molecule through: the chemical has been permeating at a rising rate before it, which is why the database carries the standard's warning that it can be dangerous to base safe wear time on the breakthrough time alone. ASTM F739 records breakthrough at 0.1 µg/cm²/min; EN ISO 6529 offers both rates, and the 1.0 figure is the one used for EN classes, so an ASTM time cannot be classed here. The cumulative estimate applies the steady-state rate to every minute after breakthrough and ignores permeation before it; the real curve climbs to the plateau rather than jumping, so the figure is a planning estimate, high in the first minutes after breakthrough and low if the rate is still rising. **Class, dose limit and wear time are the safety adviser's decision; this is a reading aid for the test report.**
  • Every input is bounded to the range normal practice occupies (Normalised Breakthrough Time 0 to 2000 min, Steady-State Permeation Rate 0.1 to 10000 µg/cm²/min and Report Uses the ASTM F739 Criterion 0 to 1 1 = yes, and so on for the rest). Those bounds are guard rails against typing errors, not a claim that the formula fails one unit outside them.
  • The calculation is deterministic: the same inputs always give the same result. It carries no allowance for machine condition, operator skill, ambient conditions or lot-to-lot material variation unless an input above explicitly represents one.
  • Nothing is sent anywhere. The maths runs in your browser, so the numbers you type never leave the page.

Standards and further reading

  • EN 14325, Protective clothing against chemicals: test methods and performance classification of chemical protective clothing materials, seams, joins and assemblages (clause 4.11, permeation classes).
  • EN ISO 6529, Protective clothing, protection against chemicals: determination of resistance of protective clothing materials to permeation by liquids and gases.
  • ASTM F739, Standard Test Method for Permeation of Liquids and Gases through Protective Clothing Materials under Conditions of Continuous Contact: breakthrough at 0.1 µg/cm²/min.
  • EN 14605, EN ISO 13982-1 and EN 13034: the Type 3 and 4, Type 5 and Type 6 suit standards that call up the EN 14325 classes.

Questions people ask

Is Class 6 a safe wear time of eight hours?

No. It says the rate did not reach 1.0 µg/cm²/min within 480 minutes under test conditions. The chemical was permeating below that rate before then, and the test knows nothing about your dose limit, temperature or the mechanical state of the suit.

Why can an ASTM F739 time not be classed?

F739 records breakthrough at 0.1 µg/cm²/min, ten times lower than the EN criterion, so the same fabric reports a shorter time. The two are not interchangeable; ask the lab for the EN figure.

Where does the steady-state rate come from?

From the permeation curve in the full report, after the rate levels out. A database that lists only breakthrough times does not have it; 1.0 is then the lowest the rate can be at breakthrough, and the estimate is a floor.

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