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Surface Chemistry

Superhydrophobic Finish Contact Angle & Roll-off Predictor

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See what it looks like

Chemistry stops at 120 degrees. Everything past that is geometry — and a surface can read 160 degrees and still hold the drop fast.

Surface Texture & chemistry
°

On a smooth surface of the same chemistry.

%
r
°
Droplet Test drop
µL
mN/m
kg/m³

Apparent Contact Angle

— °

Cassie-Baxter angle with the drop bridging the texture

Wetting Behaviour

Wenzel State Angle
— °
Roll-off Tilt Angle
— °
Solid Contact
— %
Droplet Radius
— mm
Retention Force
— µN

The Cassie state is metastable, and that is the practical problem with superhydrophobic textiles rather than a footnote to it. Pressure, impact, condensation within the texture or a surfactant in the water can all collapse the drop into the Wenzel state, at which point the same surface becomes more wettable than a smooth one would have been — which is why the Wenzel angle is shown alongside. A Wenzel result of 180 degrees means the roughness term is out of range and that state is simply not defined for this combination. Roll-off assumes a drop large enough for gravity to matter and a uniform texture; small drops pin regardless of angle. Durability is the other omission — texture that survives a laboratory drop rarely survives abrasion and laundering.

Using this calculator

About the Superhydrophobic Finish Contact Angle & Roll-off Predictor

The formula

This is the expression the tool evaluates. Every term is named underneath, with the unit it must be supplied in.

Apparent Contact Angle
cassieAngle = f( youngAngle, solidFraction, roughnessFactor, hysteresis, dropletVolume, surfaceTension, waterDensity )

Each input feeds the expression evaluated in the browser; the symbol table below names every term and its unit.

Symbols used above
SymbolStands forUnit
youngAngleIntrinsic Contact Angle°
solidFractionSolid Contact Fraction%
roughnessFactorWenzel Roughness Factorr
hysteresisContact Angle Hysteresis°
dropletVolumeDroplet VolumeµL
surfaceTensionLiquid Surface TensionmN/m
waterDensityLiquid Densitykg/m³
cassieAngleApparent Contact Angle°
wenzelAngleWenzel State Angle°
rollOffAngleRoll-off Tilt Angle°
solidContactFractionSolid Contact%
dropletRadiusDroplet Radiusmm
adhesionForceRetention ForceµN

How the result is derived

Step by step, from the values you type to the figure on screen.

  1. The 7 inputs are read from the form on every keystroke: Intrinsic Contact Angle, Solid Contact Fraction, Wenzel Roughness Factor, Contact Angle Hysteresis, Droplet Volume, Liquid Surface Tension and Liquid Density.
  2. Each value is checked against the accepted range in the input table below. A value outside its range stops the calculation rather than producing a misleading figure — the results blank out and a message appears.
  3. The validated values are substituted into the expression above, which resolves Apparent Contact Angle together with every supporting figure in one pass — no value is carried over from a previous entry.
  4. The supporting outputs — Wenzel State Angle, Roll-off Tilt Angle, Solid Contact, Droplet Radius and Retention Force — come from the same pass, so they always describe the same case as the headline figure.
  5. Results are rounded for display only. The full-precision value is used throughout the chain, so reading a rounded intermediate figure back into the tool by hand can shift the last digit.

What each input means

Where to read each value on the floor, the unit it must be in, and the range the tool accepts.

InputUnitAccepted rangeDefaultWhat it means
Intrinsic Contact Angle°60 to 130 °110On a smooth surface of the same chemistry.
Solid Contact Fraction%0.5 to 60 %5
Wenzel Roughness Factorr1 to 12 r3
Contact Angle Hysteresis°0.5 to 60 °5
Droplet VolumeµL1 to 100 µL10
Liquid Surface TensionmN/m20 to 80 mN/m72.8
Liquid Densitykg/m³700 to 1400 kg/m³1000

What the tool returns

The headline figure and every supporting value it is built from.

OutputUnitWhat it tells you
Apparent Contact Angle (headline result)°Cassie-Baxter angle with the drop bridging the texture
Wenzel State Angle°
Roll-off Tilt Angle°
Solid Contact%
Droplet Radiusmm
Retention ForceµN

Worked example

Given

Intrinsic Contact Angle
110 °
Solid Contact Fraction
5 %
Wenzel Roughness Factor
3 r
Contact Angle Hysteresis
5 °
Droplet Volume
10 µL
Liquid Surface Tension
72.8 mN/m
Liquid Density
1000 kg/m³

The tool loads with this case already solved — the Apparent Contact Angle shown above is its answer. Change one value and the difference from this baseline is the sensitivity of the result to that variable.

How to use it

  1. Work through the input groups in order — Surface and Droplet. The defaults are a realistic case, so you can change one value at a time and watch what moves.
  2. There is no calculate button. Every figure recalculates as you type or drag, which is what makes this usable for a what-if sweep rather than a single answer.
  3. Read Apparent Contact Angle in the dark results panel — that is the headline figure, expressed in °.
  4. Check the supporting rows underneath (Wenzel State Angle, Roll-off Tilt Angle, Solid Contact, Droplet Radius and Retention Force) before acting on the headline — they are where an implausible input usually shows itself first.
  5. Reset to defaults returns every field to the reference case, which is the quickest way to check whether a surprising result came from the tool or from an input you had changed earlier.

Where this is used

  • Process planning — establishing Apparent Contact Angle before a trial is booked, so machine time and material in Specialized Chemistry & Advanced Dye Physics are committed against a calculated figure rather than an estimate.
  • Costing and quotation — Apparent Contact Angle is an input to the cost sheet, and quoting from a worked number rather than a remembered one is what keeps a margin intact.
  • Troubleshooting — when the floor result drifts from plan, entering the measured values (starting with Intrinsic Contact Angle) shows how much of the gap in Apparent Contact Angle each variable explains.
  • Teaching and study — the accepted ranges bracket normal Specialized Chemistry & Advanced Dye Physics practice, so moving one variable at a time shows the shape of the relationship rather than a single answer.

Assumptions and limits

  • The Cassie state is metastable, and that is the practical problem with superhydrophobic textiles rather than a footnote to it. Pressure, impact, condensation within the texture or a surfactant in the water can all collapse the drop into the Wenzel state, at which point the same surface becomes more wettable than a smooth one would have been — which is why the Wenzel angle is shown alongside. A Wenzel result of 180 degrees means the roughness term is out of range and that state is simply not defined for this combination. Roll-off assumes a drop large enough for gravity to matter and a uniform texture; small drops pin regardless of angle. Durability is the other omission — texture that survives a laboratory drop rarely survives abrasion and laundering.
  • Every input is bounded to the range normal practice occupies (Intrinsic Contact Angle 60 to 130 °, Solid Contact Fraction 0.5 to 60 % and Wenzel Roughness Factor 1 to 12 r, and so on for the rest). Those bounds are guard rails against typing errors, not a claim that the formula fails one unit outside them.
  • The calculation is deterministic: the same inputs always give the same result. It carries no allowance for machine condition, operator skill, ambient conditions or lot-to-lot material variation unless an input above explicitly represents one.
  • Nothing is sent anywhere. The maths runs in your browser, so the numbers you type never leave the page.

Questions people ask

What do I need to know before using the Superhydrophobic Finish Contact Angle & Roll-off Predictor?

Have these to hand: Intrinsic Contact Angle, Solid Contact Fraction, Wenzel Roughness Factor, Contact Angle Hysteresis, Droplet Volume, Liquid Surface Tension and Liquid Density. With those entered, the tool returns Apparent Contact Angle immediately.

What exactly is Apparent Contact Angle?

Cassie-Baxter angle with the drop bridging the texture. It is reported in °. It is derived from Intrinsic Contact Angle, Solid Contact Fraction, Wenzel Roughness Factor, Contact Angle Hysteresis, Droplet Volume, Liquid Surface Tension and Liquid Density, and is the figure the rest of the Specialized Chemistry & Advanced Dye Physics calculation is built around.

Which units does this calculator expect?

Enter Intrinsic Contact Angle in °, Solid Contact Fraction in %, Wenzel Roughness Factor in r, Contact Angle Hysteresis in °, Droplet Volume in µL, Liquid Surface Tension in mN/m and Liquid Density in kg/m³. Mixing unit systems is the most common cause of a result that looks an order of magnitude wrong — convert before typing, not after reading.

What are the other figures under the main result?

They are the intermediate quantities the calculation passes through: Wenzel State Angle, Roll-off Tilt Angle, Solid Contact, Droplet Radius and Retention Force. They are shown because a headline number nobody can trace is a number nobody trusts — checking them against your own expectation is the fastest way to confirm the inputs were read as you intended.

Can I rely on this for a production decision?

The Cassie state is metastable, and that is the practical problem with superhydrophobic textiles rather than a footnote to it. Pressure, impact, condensation within the texture or a surfactant in the water can all collapse the drop into the Wenzel state, at which point the same surface becomes more wettable than a smooth one would have been — which is why the Wenzel angle is shown alongside. A Wenzel result of 180 degrees means the roughness term is out of range and that state is simply not defined for this combination. Roll-off assumes a drop large enough for gravity to matter and a uniform texture; small drops pin regardless of angle. Durability is the other omission — texture that survives a laboratory drop rarely survives abrasion and laundering. Treat the output as an engineering estimate that narrows the trial window, not as a substitute for the trial.

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