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Supercritical CO₂ Dyeing Pressure & Solubility Modeler

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See what it looks like

There is no water and no liquor ratio — but there is still a bath, and its capacity is set by CO₂ density rather than by volume.

Vessel Conditions Supercritical
bar
°C
kg/m³

Read from a CO₂ density chart at the working pressure and temperature.

L
Chrastil Constants Per dye
K
Batch Goods
kg
% owf

Dye Solubility in CO₂

— g/L

Chrastil correlation at the working density and temperature

Vessel Balance

Dye Dissolved per Pass
— g
Dye Required
— g
Passes Required
— no.
CO₂ Charge
— kg
Equivalent Liquor Ratio
— ×
Reduced Pressure
— ×
Reduced Temperature
— ×

Chrastil constants are specific to one dye in one solvent and must come from measured solubility data. Reduced pressure and temperature below 1 mean the fluid is not supercritical and the correlation does not apply. High-pressure vessels are a regulated safety matter — this sizes a process, not a pressure system.

Using this calculator

About the Supercritical CO₂ Dyeing Pressure & Solubility Modeler

The formula

This is the expression the tool evaluates. Every term is named underneath, with the unit it must be supplied in.

Dye Solubility in CO₂
dyeSolubility = f( pressure, temperature, co2Density, vesselVolume, chrastilK, chrastilA, chrastilB, fabricWeight, dyeOwf )

Each input feeds the expression evaluated in the browser; the symbol table below names every term and its unit.

Symbols used above
SymbolStands forUnit
pressureVessel Pressurebar
temperatureVessel Temperature°C
co2DensityCO₂ Densitykg/m³
vesselVolumeVessel VolumeL
chrastilKAssociation Number k—
chrastilAConstant aK
chrastilBConstant b—
fabricWeightFabric Weightkg
dyeOwfDye Required% owf
dyeSolubilityDye Solubility in CO₂g/L
dissolvedPerPassDye Dissolved per Passg
dyeRequiredDye Requiredg
passesRequiredPasses Requiredno.
co2ChargeCO₂ Chargekg
liquorRatioEquivalentEquivalent Liquor Ratio×
reducedPressureReduced Pressure×
reducedTemperatureReduced Temperature×

How the result is derived

Step by step, from the values you type to the figure on screen.

  1. The 9 inputs are read from the form on every keystroke: Vessel Pressure, Vessel Temperature, CO₂ Density, Vessel Volume, Association Number k, Constant a, Constant b, Fabric Weight and Dye Required.
  2. Each value is checked against the accepted range in the input table below. A value outside its range stops the calculation rather than producing a misleading figure — the results blank out and a message appears.
  3. The validated values are substituted into the expression above, which resolves Dye Solubility in CO₂ together with every supporting figure in one pass — no value is carried over from a previous entry.
  4. The supporting outputs — Dye Dissolved per Pass, Dye Required, Passes Required, CO₂ Charge, Equivalent Liquor Ratio, Reduced Pressure and Reduced Temperature — come from the same pass, so they always describe the same case as the headline figure.
  5. Results are rounded for display only. The full-precision value is used throughout the chain, so reading a rounded intermediate figure back into the tool by hand can shift the last digit.

What each input means

Where to read each value on the floor, the unit it must be in, and the range the tool accepts.

InputUnitAccepted rangeDefaultWhat it means
Vessel Pressurebar74 to 600 bar250
Vessel Temperature°C32 to 200 °C120
CO₂ Densitykg/m³100 to 1100 kg/m³620Read from a CO₂ density chart at the working pressure and temperature.
Vessel VolumeL1 to 5000 L200
Association Number k—0.5 to 154
Constant aK-12000 to 0 K-3500
Constant b—-60 to 20-16
Fabric Weightkg0.5 to 2000 kg50
Dye Required% owf0.01 to 20 % owf2

What the tool returns

The headline figure and every supporting value it is built from.

OutputUnitWhat it tells you
Dye Solubility in CO₂ (headline result)g/LChrastil correlation at the working density and temperature
Dye Dissolved per Passg
Dye Requiredg
Passes Requiredno.
CO₂ Chargekg
Equivalent Liquor Ratio×
Reduced Pressure×
Reduced Temperature×

Worked example

Given

Vessel Pressure
250 bar
Vessel Temperature
120 °C
CO₂ Density
620 kg/m³
Vessel Volume
200 L
Association Number k
4
Constant a
-3500 K
Constant b
-16
Fabric Weight
50 kg
Dye Required
2 % owf

The tool loads with this case already solved — the Dye Solubility in CO₂ shown above is its answer. Change one value and the difference from this baseline is the sensitivity of the result to that variable.

How to use it

  1. Work through the input groups in order — Vessel Conditions, Chrastil Constants and Batch. The defaults are a realistic case, so you can change one value at a time and watch what moves.
  2. There is no calculate button. Every figure recalculates as you type or drag, which is what makes this usable for a what-if sweep rather than a single answer.
  3. Read Dye Solubility in CO₂ in the dark results panel — that is the headline figure, expressed in g/L.
  4. Check the supporting rows underneath (Dye Dissolved per Pass, Dye Required, Passes Required, CO₂ Charge, Equivalent Liquor Ratio, Reduced Pressure and Reduced Temperature) before acting on the headline — they are where an implausible input usually shows itself first.
  5. Reset to defaults returns every field to the reference case, which is the quickest way to check whether a surprising result came from the tool or from an input you had changed earlier.

Where this is used

  • Process planning — establishing Dye Solubility in CO₂ before a trial is booked, so machine time and material in Advanced Colour Physics & Wet Processing are committed against a calculated figure rather than an estimate.
  • Costing and quotation — Dye Solubility in CO₂ is an input to the cost sheet, and quoting from a worked number rather than a remembered one is what keeps a margin intact.
  • Troubleshooting — when the floor result drifts from plan, entering the measured values (starting with Vessel Pressure) shows how much of the gap in Dye Solubility in CO₂ each variable explains.
  • Teaching and study — the accepted ranges bracket normal Advanced Colour Physics & Wet Processing practice, so moving one variable at a time shows the shape of the relationship rather than a single answer.

Assumptions and limits

  • Chrastil constants are specific to one dye in one solvent and must come from measured solubility data. Reduced pressure and temperature below 1 mean the fluid is not supercritical and the correlation does not apply. High-pressure vessels are a regulated safety matter — this sizes a process, not a pressure system.
  • Every input is bounded to the range normal practice occupies (Vessel Pressure 74 to 600 bar, Vessel Temperature 32 to 200 °C and CO₂ Density 100 to 1100 kg/m³, and so on for the rest). Those bounds are guard rails against typing errors, not a claim that the formula fails one unit outside them.
  • The calculation is deterministic: the same inputs always give the same result. It carries no allowance for machine condition, operator skill, ambient conditions or lot-to-lot material variation unless an input above explicitly represents one.
  • Nothing is sent anywhere. The maths runs in your browser, so the numbers you type never leave the page.

Questions people ask

What do I need to know before using the Supercritical CO₂ Dyeing Pressure & Solubility Modeler?

Have these to hand: Vessel Pressure, Vessel Temperature, CO₂ Density, Vessel Volume, Association Number k, Constant a, Constant b, Fabric Weight and Dye Required. With those entered, the tool returns Dye Solubility in CO₂ immediately.

What exactly is Dye Solubility in CO₂?

Chrastil correlation at the working density and temperature. It is reported in g/L. It is derived from Vessel Pressure, Vessel Temperature, CO₂ Density, Vessel Volume, Association Number k, Constant a, Constant b, Fabric Weight and Dye Required, and is the figure the rest of the Advanced Colour Physics & Wet Processing calculation is built around.

Which units does this calculator expect?

Enter Vessel Pressure in bar, Vessel Temperature in °C, CO₂ Density in kg/m³, Vessel Volume in L, Constant a in K, Fabric Weight in kg and Dye Required in % owf. Mixing unit systems is the most common cause of a result that looks an order of magnitude wrong — convert before typing, not after reading.

What are the other figures under the main result?

They are the intermediate quantities the calculation passes through: Dye Dissolved per Pass, Dye Required, Passes Required, CO₂ Charge, Equivalent Liquor Ratio, Reduced Pressure and Reduced Temperature. They are shown because a headline number nobody can trace is a number nobody trusts — checking them against your own expectation is the fastest way to confirm the inputs were read as you intended.

Can I rely on this for a production decision?

Chrastil constants are specific to one dye in one solvent and must come from measured solubility data. Reduced pressure and temperature below 1 mean the fluid is not supercritical and the correlation does not apply. High-pressure vessels are a regulated safety matter — this sizes a process, not a pressure system. Treat the output as an engineering estimate that narrows the trial window, not as a substitute for the trial.

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