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Nanotechnology Benefits in Fabric Formation

Nanometer (Nm) resins have been shown to modify fiber behavior in existing textile yarn. Incorporation of nanometer (Nm) resins in conventional warp size formulations improve weaving performance, improve fabric quality and reduce cost.

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Background

At a symposium at the California Institute of Technology in 1959, Nobel physicist Richard Feynman proposed investigations into effects on the molecular level. The title of his presentation was “There is Plenty of Room at the Bottom” referring to research and development of very small molecules and their modifications.

This concept was presented during the time when both emphasis and financing in the chemical world was concentrated on the benefits of large synthetic polymers. In this atmosphere, Feynman’s revolutionary concept received little attention.

The term nanotechnology (10-9 meter) was proposed 15 years later by Norio Taniguchi of Tokyo University to describe laser precision grinding of metal. In 1998, Nanotex patented a water repellent fabric finish mimicking the Nm fibrils that keep plant leaves dry during rain events.  From this point, research in nanosize materials and effects advanced rapidly in academic and industrial areas worldwide.

The time between introduction and acceptance of the nanotechnology concept mirrored the lengthy period in the development of higher molecular weight synthetic polymers introduced by Carl Marvel in the 1930s.

Progress

Introduction of fabric with the patented Nanotex finish awakened the potential of nanotechnology to academia and industry. Research and Development into this technology soon appeared in diverse industries worldwide. It was a rare issue when textile publications did not announce a new nano finish for unusual results on fabric. Nanotechnology has inspired markets that had never been considered.

Warp Sizing

Woven fabric formation has not been among the beneficiaries of this developing technology. Several factors have been involved in the reluctance to pursue potentials in this area.

These factors include:

  • Woven fabric formation is basically a dry process.
  • The only major water-based step of the process involves applying a protective coating to warp yarn to resist loom abrasion.
  • The warp size process has traditionally utilized high molecular weight polymers, natural or synthetic, to provide surface protection.
  • Warp sizing is a necessary process aid not apparent to the final customer.
  • Warp size chemicals are available to all suppliers.
  • Nm resins are not good film formers and should have little effect on protective surface films.
  • At initial glance, Nm resins do not fit the traditional requirements to improve the yarn coating.

Typical Water Borne Nm resin Properties:

  • Defined as 100 Nm or less particle size.
  • High active surface area.
  • High adhesive behavior.
  • Poor film former

These properties do not point to obvious benefits in improving higher molecular weight film behavior.  Instead, these properties point to a new mechanism to take advantage of nanotechnology materials in warp sizing.

The image pictured is a cross-section of 40’s count ring spun cotton yarn at 1040X magnification. Spacing between fibers in the yarn illustrate the vacant areas in the yarn. Nm resins are magnitudes smaller than these areas and are easily carried throughout the yarn bundle by water. Nm resins immediately adhere to fiber surfaces and overwhelm normal repulsive forces that hinder a more intimate interfiber association (cohesion). Enhanced fiber cohesion in the bundle results in a more compact yarn structure. The same number of fibers in this compact structure provides improved tensile and elongation physical properties in comparison to yarn entering the size box.

Yarn Studies

Determination of the benefits of enhanced fiber cohesion within the yarn bundle without applying the size coating has presented challenges. A lack of access to sample warp size machines has complicated efforts to demonstrate these benefits. The benefits of enhanced fiber cohesion within the bundle was demonstrated by subjecting yarn to a conventional mock dye process. Nm resin product was added in the final rinse of the mock dye process.  60/40 P/C 30’s ring spun yarn was wound on dye tubes and processed through the mock dye cycle.  0.5% Nm product on yarn weight was added to the final rinse to determine any benefit.

Control and test yarns were evaluated by Statement to determine physical properties.

Mock Dye Results: Nm Resin Added in Final Rinse

ElongationMax Force g
MinCVMaxMinCVMax
Control7.2111.1010.82236.998.84338.26
0.5% Resin Product8.568.8512.45259.818.04358.60
% Difference15.77-25.4213.098.78-9.955.67
*60/40 P/C blend yarn: High water solubility of Nm resin prevents retention on cotton in the final rinse in the mock dye test.

Enhanced fiber cohesion in warp yarn is reflected in the quality and uniformity of the sized yarn.  Yarns from the creel are modified in the bundle by Nm resin molecules as higher molecular weight polymers coat the surface.  A compact yarn with improved properties is the substrate for the protective warp size coating.

Initial indications of improved fiber cohesion within the hard yarn bundle were shown during weaving in the lower warp and filling stops. Continued evaluations in commercial sizing machines demonstrated that the smoother, more compact yarn allowed increased sized yardage on the loom beam.

Enhanced cohesion between fibers in the hard yarn bundle is more resistant to disruption as the sized sheet is separated at the bust section of the machine.  Hard sized fiber pullout is reduced to provide smoother sized yarn surfaces.  Smoother hard yarn provides reduced filling stops on the loom.  Reduction in filling stops is especially apparent in air-jet weaving.

Desize of loom state fabric containing Nm resin is easily accomplished by normal procedures.

Economic Considerations:

Warp sizing is a necessary process for the efficient production of woven fabric.  Current practices have provided adhesive coatings on the yarn which provide effective abrasion protection at acceptable costs. Nm resin modification of yarn in the size bath produces a more compact yarn to host the surface coating.  Modification of the yarn to a more compact structure reduces the surface area to be protected in this process.  Yarn may be regarded as a cylinder. Euclid of Alexandria determined the surface area of a cylinder to be directly related to the radius of the cylinder.  Reduction of the surface area of the cylinder reduces the level of coating required to protect the yarn.

Photo examples of sized yarns demonstrate the Nm resin effect on yarn.  The effects of improved fiber cohesion within the bundle are demonstrated at 60X magnification.  All comparative hard yarns have equivalent add-on levels based on the standard size formation.  All yarn photos are from commercial production.

10’s Count Cotton
Spun PET
12’s Terry Pile Cotton
50/50 P/C
3 Comments
  1. JOHN LARK says

    Nano resin additives in loom state fabric present no problems in mild desize procedures. These materials are much more compatible with water than primary components of the size formulation.

  2. JOHN LARK says

    The nano resins developed for use in warp sizing applications demonstrate complete removal in conventional desize procedures at pH7 and above.

  3. ashok hakoo says

    The paper is good and knowledgeable. Monk dye result chart shows very good results by application of Nm resin.. All yarn photos indicate good and smooth surfaces ideal for weaving purposes. Complete rather all traces of resin needs to be eliminated by De-sizing of grey fabric and is very important factor especially for fabric dying operation. moreover this should be economical operation.

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