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Effluent Treatment

Effluent Colour ADMI Removal, Compliance Margin & Chemical Cost

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See what it looks like

Colour does not track COD. A plant can pass every oxygen-demand limit and still discharge visible dye.

Colour Readings Across the treatment plant
m3/d
ADMI
ADMI
ADMI

Site-specific; the two scales are not interchangeable

Chemical Dosing What achieves the removal
mg/L
/kg
mg/L
/kg

Colour Removal

— %

Inlet to outlet ADMI across the plant

Compliance, Dose & Cost

Margin to the Discharge Limit
— ADMI
Removal the Limit Demands
— %
Chemical Cost
— /m3
ADMI Removed per mg/L Dosed
—
Coagulant
— kg/d
Decolourising Agent
— kg/d
Chemical Cost
— /d
Outlet Colour in Pt-Co
— Pt-Co

ADMI is reported on a 1 cm path length at a stated pH; colour is pH-sensitive for many dye classes, so a reading taken before neutralisation is not comparable with one after it. The specific removal figure is a simple ratio and will fall as dose rises because colour removal saturates - it is a tracking metric, not a linear coefficient to extrapolate. Coagulant dose also generates sludge, which is a separate cost and is not included here. The ADMI to Pt-Co factor is site and shade specific and the two scales are not interchangeable; where a permit names one, measure that one rather than converting.

Using this calculator

About the Effluent Colour ADMI Removal, Compliance Margin & Chemical Cost

The formula

This is the expression the tool evaluates. Every term is named underneath, with the unit it must be supplied in.

Removal across the plant
colourRemovalPct = ( inletAdmi - outletAdmi ) / inletAdmi x 100

ADMI is a tristimulus colour scale derived from transmittance at multiple wavelengths, so unlike a single-wavelength absorbance it responds to hue as well as depth. That makes it comparable between shades in a way a 400 nm reading is not.

What compliance actually demands
removalRequiredPct = ( inletAdmi - dischargeLimit ) / inletAdmi x 100

Separating the removal achieved from the removal required is the point. A plant achieving 86% when 78% is required has margin; one achieving 95% when 97% is required is failing despite a better number.

Milligrams per litre to kilograms per day
coagulantKgPerDay = coagulantDose x flowM3PerDay / 1000

A mg/L dose against a flow in cubic metres per day gives grams per day directly, so the thousand converts to kilograms. At 1,200 m3/d even a modest dose becomes a substantial daily chemical bill.

Removal bought per unit of dose
specificRemoval = ( inletAdmi - outletAdmi ) / ( coagulantDose + decolouriserDose )

The figure to track when optimising, because it exposes diminishing returns. Colour removal saturates - the last few hundred ADMI cost far more per unit than the first few thousand, and the specific removal falls as the dose rises.

Symbols used above
SymbolStands forUnit
ADMIAmerican Dye Manufacturers Institute tristimulus colour unitADMI
Pt-CoPlatinum-cobalt colour scale, also called APHA or HazenPt-Co
coagulantTypically alum, ferric or a polyaluminium chloride—

How the result is derived

Step by step, from the values you type to the figure on screen.

  1. The 9 inputs are read from the form on every keystroke: Effluent Flow, Inlet Colour, Outlet Colour, Discharge Limit, ADMI to Pt-Co Factor, Coagulant Dose, Coagulant Price, Decolourising Agent Dose and Decolourising Agent Price.
  2. Each value is checked against the accepted range in the input table below. A value outside its range stops the calculation rather than producing a misleading figure — the results blank out and a message appears.
  3. The validated values are substituted into the expression above, which resolves Colour Removal together with every supporting figure in one pass — no value is carried over from a previous entry.
  4. The supporting outputs — Margin to the Discharge Limit, Removal the Limit Demands, Chemical Cost, ADMI Removed per mg/L Dosed, Coagulant, Decolourising Agent, Chemical Cost and Outlet Colour in Pt-Co — come from the same pass, so they always describe the same case as the headline figure.
  5. Results are rounded for display only. The full-precision value is used throughout the chain, so reading a rounded intermediate figure back into the tool by hand can shift the last digit.

What each input means

Where to read each value on the floor, the unit it must be in, and the range the tool accepts.

InputUnitAccepted rangeDefaultWhat it means
Effluent Flowm3/d10 to 50000 m3/d1200
Inlet ColourADMI50 to 20000 ADMI1800
Outlet ColourADMI1 to 20000 ADMI250
Discharge LimitADMI10 to 5000 ADMI400
ADMI to Pt-Co Factor—0.3 to 30.9Site-specific; the two scales are not interchangeable
Coagulant Dosemg/L0 to 1500 mg/L180
Coagulant Price/kg0.01 to 20 /kg0.42
Decolourising Agent Dosemg/L0 to 500 mg/L25
Decolourising Agent Price/kg0.01 to 60 /kg2.8

What the tool returns

The headline figure and every supporting value it is built from.

OutputUnitWhat it tells you
Colour Removal (headline result)%Inlet to outlet ADMI across the plant
Margin to the Discharge LimitADMI
Removal the Limit Demands%
Chemical Cost/m3
ADMI Removed per mg/L Dosed—
Coagulantkg/d
Decolourising Agentkg/d
Chemical Cost/d
Outlet Colour in Pt-CoPt-Co

Worked example

Given

0
1,200 m3/d flow, inlet 1,800 ADMI, outlet 250 ADMI
1
Discharge limit 400 ADMI
2
180 mg/L coagulant at 0.42/kg, 25 mg/L decolouriser at 2.80/kg
3
ADMI to Pt-Co factor 0.9

Substituting

removal = (1,800 - 250) / 1,800 = 86.1111%required = (1,800 - 400) / 1,800 = 77.7778%coagulant = 180 x 1,200 / 1,000 = 216 kg/dcost = 216 x 0.42 + 30 x 2.80 = 90.72 + 84.00 = 174.72/dspecific = (1,800 - 250) / (180 + 25) = 7.561 ADMI per mg/L

Answer

0
Colour removal 86.1111%, against 77.7778% required
1
150 ADMI of compliance margin
2
216 kg/d coagulant and 30 kg/d decolouriser
3
174.72 a day, or 0.1456 per cubic metre
4
7.561 ADMI removed per mg/L dosed; outlet 225 Pt-Co

The decolourising agent is 12% of the dose by mass and 48% of the cost, which is where any optimisation should start. And note the two removal figures: 86% achieved against 78% required is real margin, so there is room to trim the expensive half of the dose - the specific removal figure is what tells you when trimming has gone too far.

How to use it

  1. Work through the input groups in order — Colour Readings and Chemical Dosing. The defaults are a realistic case, so you can change one value at a time and watch what moves.
  2. There is no calculate button. Every figure recalculates as you type or drag, which is what makes this usable for a what-if sweep rather than a single answer.
  3. Read Colour Removal in the dark results panel — that is the headline figure, expressed in %.
  4. Check the supporting rows underneath (Margin to the Discharge Limit, Removal the Limit Demands, Chemical Cost, ADMI Removed per mg/L Dosed, Coagulant, Decolourising Agent, Chemical Cost and Outlet Colour in Pt-Co) before acting on the headline — they are where an implausible input usually shows itself first.
  5. Reset to defaults returns every field to the reference case, which is the quickest way to check whether a surprising result came from the tool or from an input you had changed earlier.

Where this is used

  • Process planning — establishing Colour Removal before a trial is booked, so machine time and material in Sustainability, ETP & Utilities are committed against a calculated figure rather than an estimate.
  • Costing and quotation — Colour Removal is an input to the cost sheet, and quoting from a worked number rather than a remembered one is what keeps a margin intact.
  • Troubleshooting — when the floor result drifts from plan, entering the measured values (starting with Effluent Flow) shows how much of the gap in Colour Removal each variable explains.
  • Teaching and study — the accepted ranges bracket normal Sustainability, ETP & Utilities practice, so moving one variable at a time shows the shape of the relationship rather than a single answer.

Reading the result

Typical bands and what each one is telling you.

ValueWhat it indicates
1,000 - 3,000 ADMI inletTypical mixed dyehouse effluent after equalisation.
150 - 400 ADMI discharge limitCommon regulatory range; some jurisdictions specify Pt-Co instead.
80 - 95% removalAchievable with coagulation plus a decolourising polymer.
Above 95% removalUsually needs ozone, activated carbon or membrane polishing, at a step change in cost.

Assumptions and limits

  • ADMI is reported on a 1 cm path length at a stated pH; colour is pH-sensitive for many dye classes, so a reading taken before neutralisation is not comparable with one after it. The specific removal figure is a simple ratio and will fall as dose rises because colour removal saturates - it is a tracking metric, not a linear coefficient to extrapolate. Coagulant dose also generates sludge, which is a separate cost and is not included here. The ADMI to Pt-Co factor is site and shade specific and the two scales are not interchangeable; where a permit names one, measure that one rather than converting.
  • Every input is bounded to the range normal practice occupies (Effluent Flow 10 to 50000 m3/d, Inlet Colour 50 to 20000 ADMI and Outlet Colour 1 to 20000 ADMI, and so on for the rest). Those bounds are guard rails against typing errors, not a claim that the formula fails one unit outside them.
  • The calculation is deterministic: the same inputs always give the same result. It carries no allowance for machine condition, operator skill, ambient conditions or lot-to-lot material variation unless an input above explicitly represents one.
  • Nothing is sent anywhere. The maths runs in your browser, so the numbers you type never leave the page.

Standards and further reading

  • ADMI 3-wavelength method, Standard Methods for the Examination of Water and Wastewater 2120 F.
  • APHA platinum-cobalt visual method, Standard Methods 2120 B, for the Pt-Co scale.
  • ISO 7887 - Water quality, examination and determination of colour.
  • ZDHC Wastewater Guidelines, which set colour among the conventional parameters.

Questions people ask

Why does colour need its own limit when COD is already controlled?

Because the two do not correlate. Reactive dye hydrolysed in the bath is highly coloured and only weakly biodegradable, so it passes through biological treatment largely intact - COD falls while colour does not. A plant can discharge water meeting every oxygen-demand limit that is still visibly dyed, and colour is the parameter a regulator or a downstream community notices first. It is also why colour removal is usually a separate physico-chemical step rather than something the aeration basin achieves.

Are ADMI and Pt-Co interchangeable?

No, and the conversion factor here is deliberately an input rather than a constant. Pt-Co is a visual comparison against a yellow-brown platinum-cobalt standard and responds mainly to yellow hues; ADMI is a tristimulus calculation from transmittance at multiple wavelengths and responds to any hue. For a yellow-brown effluent they track reasonably; for a blue or red discharge they diverge sharply, and a factor fitted on one shade will mislead on another. Where a permit specifies one scale, measure that scale.

The decolouriser is a small part of the dose. Why does it dominate the cost?

Because the two chemicals do different jobs at very different prices. Coagulant is cheap bulk inorganic chemistry that removes colour by sweep flocculation, dragging dye down with the floc. A decolourising agent is a cationic polymer that binds anionic dye directly and is an order of magnitude more expensive per kilogram. Here it is 12% of the mass and 48% of the cost, so any dose optimisation should start with the polymer and use the specific removal figure to find where trimming it starts costing compliance margin.

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