Natural Cellulose Fibers – natures own fibers
Cellulose is a fibrous material of plant origin and the basis of all natural and man-made cellulosic fibers. The natural cellulosic fibers include cotton, flax, hemp, jute, and ramie. Cellulose is a polymeric sugar polysaccharide) made up of repeating 1,4-8-an hydro glucose units connected to each other by 8-ether linkages. Strong intermolecular forces between chains, coupled with the high linearity of the cellulose molecule, account for the crystalline nature of cellulosic fibres.
The natural fibers are vegetable, animal, or mineral in origin. Vegetable fibers, as the name implies, are derived from plants. The principal chemical component in plants is cellulose, and therefore they are also referred to as cellulosic fibers.
The fibers are usually bound by a natural phenolic polymer, lignin, which also is frequently present in the cell wall of the fiber; thus vegetable fibers are also often referred to as lignocellulosic fibers, except for cotton, which does not contain lignin.
Cellulose is a fibrous material of plant Origin and the basis of all natural and man-made cellulosic fibers. The natural cellulosic fibers include cotton, flax, hemp, jute, and ramie. The major man-made cellulosic fiber is rayon, a fiber produced by regeneration of dissolved forms of cellulose.
Cellulose is a polymeric sugar (polysaccharide) made up of repeating 1,4-8-an hydro glucose units connected to each other by 8-ether linkages.
The long 1inear chains of cellulose permit the hydroxyl functional groups on each anhydrous glucose unit to interact with hydroxyl groups on adjacent chains through hydrogen bonding and van der Waal s forces. These strong intermolecular forces between chains, coupled with the high linearity of the cellulose molecule, account for the crystalline nature of cellulosic fibers.
|Cotton is the most commonly used natural cellulosic fiber. Cotton fibers grow from the seeds in the boll (seedpod). Each boll contains seven or eight seeds, and each seed may have up to 20,000 fibers growing from it.|
|Coir is from the fibrous mass between the outer shell and husk of coconuts. It is a stiff fiber. It is usually used to make highly durable indoor and outdoor mats, rugs, and tiles.|
|Kapok fiber is from the seed of the Java or Indian kapok tree. The fiber is soft, lightweight, and hollow. It breaks down easily and it is difficult to spin into yarns. It is used as fiberfill and as the stuffing for pillows. It used to be used as a stuffing for lifejackets and the mattresses on cruise ships because it is very buoyant.|
|Milkweed has properties similar to those of kapok.|
|Flax is one of the oldest textile fibers, but its use has declined since the invention of power spinning for cotton. Flax fabric is linen, although the word linen is now often used to refer to table, bed, and bath fabrics made from other materials|
|Ramie fibers are 4 to 6 inches long. The fibers are whiter and softer than flax. Ramie does not retain dyes well unless it is dry-cleaned. Ramie is strong for a natural fiber, but it lacks resiliency, elasticity, and elongation potential. It is resistant to mildew, insects, and shrinkage. It is used for apparel, window treatments, ropes, paper, and table and bed linens|
|Hemp is similar to flax. The fibers range in length from 3 to 15 feet. Hemp production is illegal in the U.S. Hemp has a low environmental impact; it does not require pesticides. It produces 250% more fiber than cotton and 600% more fiber than flax on the same amount of land. Hemp plants can be used to extract zinc and mercury pollutants from soil. Hemp is used for ropes, apparel, and paper. Potheads are willing to pay inflated prices for hemp apparel because it is related to the marijuana plant|
|Jute is one of the cheapest textile fibers, and one of the weakest cellulosic fibers. Jute has poor elasticity, elongation, sunlight resistance, mildew resistance, and colorfastness. It is used to produce sugar and coffee bagging, carpet backing, rope, and wall coverings. Burlap is made from jute.|
|Piña fibers are from the leaves of the pineapple plant. It is used to make lightweight, sheer, stiff fabrics for apparel, bags, and table linens. It is also used to make mats.|
|Abaca is from a member of the banana tree family. The fibers are coarse and very long (up to 15 feet). It is a strong, durable, and flexible fiber used for ropes, floor mats, table linens, apparel, and wicker furniture.|
Classification of Vegetable Fibers
- Vegetable fibers are classified according to their source in plants as follows:
(1) the bast or stem fibers, which form the fibrous bundles in the inner bark (phloem or bast) of the plant stems, are often referred to as soft fibers for textile use;
- (2) the leaf fibers, which run lengthwise through the leaves of monocotyledonous plants, are also referred to as hard fibers; and
- (3) the seed-hair fibers, the source of cotton, which is the most important vegetable fiber. There are >250,000 species of higher plants; however, only a very limited number of species have been exploited for commercial uses (<0.1%).
The fibers in bast and leaf fiber plants are integral to the plant structure, providing strength and support. In bast fiber plants, the fibers are next to the outer bark in the bast or phloem and serve to strengthen the stems of these reed-like plants.
The fibers are in strands running the length of the stem or between joints. To separate the strands, the natural gum binding them must be removed. This operation is called retting (controlled rotting).
For most uses, particularly for textiles, this long composite-type strand fiber is used directly; however, when such fiber strands are pulped by chemical means the strand is broken down into much shorter and finer fibers, the ultimate fibers.
The long leaf-fibers contribute strength to the leaves of certain nonwoody, monocotyledonous plants. They extend longitudinally the full length of the leaf and are buried in tissues of a parenchymatous nature. The fibers found nearest the leaf surface are the strongest.
The fibers are separated from the pulp tissue by scraping because there is little bonding between fiber and pulp; this operation is called decortication. Leaf fiber strands are also multicelled in structure.
Ancient humans used cordage in fishing, trapping, and transport, and in fabrics for clothing. Rope and cord making started in Paleolithic times, as seen in cave drawings. Rope, cords, and fabrics were made from reeds and grasses in ancient Egypt (400 BC). Ropes, boats, sails, and mats were made from palm leaf fibers and papyrus stalks and writing surfaces, known as papyrus, from the pith section.
Jute, flax, ramie, sedges, rushes, and reeds have long been used for fabrics and baskets. Jute was cultivated in India in ancient times and used for spinning and weaving. The first true paper is believed to have been made in southeastern China in the second century AD from old rags (bast fibers) of hemp and ramie and later from the bast fiber of the mulberry tree.
World markets for vegetable fibers have been steadily declining in recent years, mainly as a result of substitution with synthetic materials.
Jute has traditionally been one of the principal bast fibers (tonnage basis) sold on the world market; however, the precipitous decline in jute exports by India indicate the decreasing market demand for this fiber that has been vitally important to the economies of India (West Bengal), Bangladesh, and Pakistan.
Natural Cellulosic Fiber Characteristics